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Silicon nitride ceramic is an inorganic material ceramic that does not shrink when sintered. Silicon nitride is very strong, especially hot pressed silicon nitride, which is one of the hardest substances in the world. It has high strength, low density and high temperature resistance.
Si3N4 ceramic is a covalent bond compound. The basic structural unit is a [SiN4] tetrahedron. The silicon atom is located at the center of the tetrahedron. There are four nitrogen atoms around it, which are located at the four vertices of the tetrahedron, and then every three A tetrahedron shares the form of an atom, forming a continuous and robust network structure in three dimensions.
Basic nature
Many of the properties of silicon nitride are attributed to this structure. Pure Si3N4 is 3119, with both α and β crystal structures, all of which are hexagonal crystals. The decomposition temperature is 1800 ° C in air and 1850 ° C in 011 MPa nitrogen. Si3N4 has a low thermal expansion coefficient and a high thermal conductivity, so its thermal shock resistance is excellent. The hot-pressed sintered silicon nitride is heated to l000 ° C and then put into cold water without cracking. At less high temperatures, Si3N4 has higher strength and impact resistance, but it will break with the increase of use time above 1200 °C, which will reduce its strength and fatigue damage will occur more than 1450 °C, so Si3N4 The use temperature generally does not exceed 1300 ° C. Due to the low theoretical density of Si3N4, it is much lighter than steel and engineering superalloy steel. Therefore, it is better to use Si3N4 ceramic instead of alloy steel in places where high strength, low density and high temperature resistance are required. It is.
Material properties
As an excellent high-temperature engineering material, Si3N4 ceramic material has the most advantage in its application in high temperature fields. The future development direction of Si3N4 is: (1) to fully utilize and utilize the excellent characteristics of Si3N4 itself; (2) to develop some new flux during the sintering of Si3N4 powder, to study and control the optimal composition of existing flux; (3) to improve milling , molding and sintering process; (4) development of Si3N4 and SiC and other materials, in order to obtain more high-performance composite materials. The application of Si3N4 ceramics on automotive engines has opened up a new dimension for the development of new high-temperature structural materials. The automobile industry itself is a multidisciplinary industry that integrates all kinds of science and technology. China is an ancient civilization with a long history. It has made brilliant achievements in the history of ceramic development. With the progress of reform and opening up, one day, China also It is bound to be among the world's major auto industry countries, creating new glory for the development of ceramics.
It is extremely resistant to high temperatures, its strength can be maintained to a high temperature of 1200 °C without falling, it will not melt into a melt after heating, it will decompose until 1900 °C, and it has amazing chemical resistance and can withstand almost all inorganic acids. And less than 30% caustic soda solution can also resist the corrosion of many organic acids; at the same time it is a high-performance electrical insulation material.
Related applications
Utilizing the light weight and high stiffness of the Si3N4, it can be used to make ball bearings, which have higher precision than metal bearings, generate less heat, and operate in higher temperature and corrosive media. The steam nozzle made of Si3N4 ceramic has the characteristics of wear resistance and heat resistance. It is used for 650 °C boiler without obvious damage after several months, while other heat-resistant and corrosion-resistant alloy steel nozzle can only be used for 1-2 months under the same conditions. The Si3N4 glow plug jointly developed by the Shanghai Institute of Ceramics of the Chinese Academy of Sciences and the Shanghai Internal Combustion Engine Research Institute of the Ministry of Electrical and Mechanical Engineering solves the problem of the difficulty of cold start of the diesel engine and is suitable for direct injection or non-direct injection diesel engines. This glow plug is the most advanced and ideal diesel engine ignition device available today. The Japan Atomic Energy Research Institute and Mitsubishi Heavy Industries Co., Ltd. have developed a new crude pump with a rotor consisting of 11 Si3N4 ceramic turntables. Because the pump uses a Si3N4 ceramic rotor with a small coefficient of thermal expansion and a precision air bearing, it can operate normally without lubrication and cooling media. If this pump is combined with an ultra-vacuum pump such as a turbo-molecular pump, it can form a vacuum system suitable for use in nuclear fusion reactors or semiconductor processing equipment.
The above are just a few examples of Si3N4 ceramics as structural materials. It is believed that with the improvement of Si3N4 powder production, molding, sintering and processing technology, its performance and reliability will continue to improve, and silicon nitride ceramics will be more widely used. Due to the improvement of the purity of Si3N4 raw materials, the rapid development of Si3N4 powder forming technology and sintering technology, and the expanding application fields, Si3N4 is playing an increasingly important role in the industry as an engineering structural ceramic. Si3N4 ceramics is an ideal high-temperature structural material with excellent comprehensive performance and abundant resources. It has a wide range of application fields and markets, and all countries in the world are competing for research and development. Ceramic materials have the characteristics of wear resistance, corrosion resistance, high temperature resistance, oxidation resistance, thermal shock resistance and low specific gravity which are difficult to compare with general metal materials. It can withstand the harsh working environment where metal or polymer materials are difficult to handle, and has broad application prospects. It has become a key basic material supporting the 21st century pillar industry after metal materials and polymer materials, and has become one of the most active research fields. Today, all countries in the world attach great importance to its research and development, and as an important member of the high temperature structural ceramic family. A Si3N4 ceramic has better mechanical properties, thermal properties and chemical stability than other high-temperature structural ceramics such as oxide ceramics and carbide ceramics. Therefore, it is considered to be the most promising material in high-temperature structural ceramics.
Product parameters
The company mainly produces hot-sintered silicon nitride. The bulk density (g/cm3) of the product is between 3.2 and 3.3, the hardness (HRA) is between 90 and 92, and the flexural strength (MPa) is between 800 and 1200. The maximum working temperature (°C) is 800 °C.